You will be fine - you could start it - HOWEVER - remember, it's income - and although she won't be entitled to the business, your extra income *could* become a factor on your alimony & child support since your divorce is not final yet. I suggest you wait until things are final, that way, CS can't be reviewed for at least 36 months as I doubt your new start up will increase your salary to the point your CS would be 10% higher than it is set to right now, and it will give you a cushion of time to get things going.
Better safe than sorry...
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